Hydrogenation of toluene on the promoted natural zeolite of Shankanay field

  • R. Moisa Scientific Research Institute for New Chemical Technologies and Materials, Almaty
  • Gulzira Vasilina al-Farabi Kazakh National University
  • Zhaksyntay Kairbekov al-Farabi Kazakh National University
  • Anatoliy Kupchishin Abai Kazakh National Pedagogical University, Almaty
  • A. Temirkhan al-Farabi Kazakh National University
Keywords: hydrogenation of aromatic hydrocarbons, zeolite catalysts, irradiation metal inflicted catalysts, Shankanay field's zeolite


Effect of dose and condition of electron irradiation on phisical-chemical characteristics and activity of catalysts on the based zeolite of Shankanay fields inflicted on oxide of alumina and promoted with 5 % Ni and 5 % WO3 in the process of toluene hydrogenation was stadied. It was found that on activity of catalyst 5 % Ni-5 % WO3/zeolite from Shankanay field inflicted on oxide of alumina affects condition, dose of irradiation and temperature of the hydrogenation. Most mild conditions (1500C) 100 % of conversion of toluene was observed in the pre-irradiated catalyst in oxidizing condition with a dose of 100 MRad.


1. Nagy G., Varga Z., Kallo D., Hancsok J. Investigation of hydrogenation of aromatic hydrocarbons on Pt/Pd/USY catalyst. Hungarian Journal of industrial chemistry, 2009, no. 2. P. 69-75.

2. Lysenko S.V., Baranova S.V., Maksimova A.L., Kardasheva S.V., Kulikov A.B., Shirokopoyas S.I., Ostroumova V.A., Petrov Yu N. and Karakhanov E. A. Hydrogenation of Aromatic Compounds in the Presence of Dibenzothiophene over Bimetallic Catalysts Containing Mesoporous Aluminosilicates. Petroleum Chemistry, 2013, no 2. P. 97-101.

3. SolovetskyYu.I. MarkaryanG.L., LuninaE.V.,Ryabchenko P.V., Seleznev Yu. L., Lunin V.V.Radiation heat treatment of catalysts of production of sulfur in the process of Claus [Radiatsionno-termicheskaya obrabotka katalizatorov proizvodstva sery v protcesse Klausa]. Kinetika I kataliz –Kinetics and Catalysis,1994, no. 2. P. 311-313.

4. Li C.P., Proctor A., Hercules D.M. Curve fitting analysis of ESCA Ni2p spectra of nickel-oxygen compounds and Ni /Al2O3 catalysts. Appl. Spectrosc, 1984. P. 880-886.

How to Cite
Moisa, R., Vasilina, G., Kairbekov, Z., Kupchishin, A., & Temirkhan, A. (2013). Hydrogenation of toluene on the promoted natural zeolite of Shankanay field. Chemical Bulletin of Kazakh National University, 71(3), 83-89. https://doi.org/https://doi.org/10.15328/chemb_2013_383-89