Kinetics of the oxidative hydroxylation of sodium hypophosphite in the presence of copper (II) chloride modified by humic (fulvo-) acid

  • Zhaksyntay Kairbekov al-Farabi Kazakh National University
  • Dina Akbayeva al-Farabi Kazakh National University
  • Zhaniya Eshova al-Farabi Kazakh National University
  • M. Bazhanovа al-Farabi Kazakh National University
DOI: https://doi.org/10.15328/chemb_2012_438-41
Keywords: sodium hypophosphite, oxidation, oxygen, humic (fulvo-) acid, hydroxylation, phosphorous acid, kinetics, optimum conditions

Abstract

It was established that in soft conditions (50-70oC, PO2 = 1 atm) sodium hypophosphite effectively is oxidized by oxygen in water solutions of copper(II) chloride  to give mainly a phosphorous acid. Humic (fulvo-) acid was extracted from brown coal of domestic deposit Kiyakty. For determination of optimum parameters of fulvo-acid extraction the laboratory experiments were carried out using the method of experiment planning. The kinetics, the intermediate and final products, optimal conditions of new catalytic reaction of NaH2PO2 oxidation by oxygen in water solution were defined by kinetics, volumometry, redox-potentiometry and a titration.

References

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Published
2012-12-04
How to Cite
Kairbekov, Z., Akbayeva, D., Eshova, Z., & BazhanovаM. (2012). Kinetics of the oxidative hydroxylation of sodium hypophosphite in the presence of copper (II) chloride modified by humic (fulvo-) acid. Chemical Bulletin of Kazakh National University, 68(4), 38-41. https://doi.org/https://doi.org/10.15328/chemb_2012_438-41
Issue
Vol 68 No 4 (2012): Chemical Bulletin of Kazakh National University
Section
Other Papers
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