Synthesis of olefins and oxygen containing mixtures from C3–C4 alkanes
Abstract
Oxidative conversion of propane–butane mixture into C2 – C4 olefins and oxygen–containing compositions over polyoxide catalysts on a basis of Mo heteropoly compounds was investigated. The influence of technological parameters and composition of catalysts on conversion and selectivity on target products were determined.
References
2. Van Camp C. The future of the petrochemical industry in Europe // Catalysis Today. 2005. Vol.106, № 1–4. P.15–29.
3. Давыдов А.А., Гончарова О.И. Применение ИК–спектроскопии для исследования катализаторов на основе гетерополимолибденовых соединений, нанесенных на оксиды // Успехи химии. 1993. Т.62, №2. С.118–134.
4. Савельева Г.А., Сасс А.С., Досумов К., Оразымбетова С.Д., Бекбатырова Г.М.
Структурные превращения нанесенных гетерополисоединений в реакции окислительной конверсии алканов под влиянием среды // Механизмы каталитических реакций: VI Российская конф. –Новосибирск, 2002. С.284–285.
5. Mizuno N., Tateishi M., Iwamoto M. Enhancement of catalytic activity of Cs2.5Ni0.08H0.34PMo12O40 by V5+–substitution for oxidation of isobutane into methacrylic acid // Applied Catalysis A: General. 1994. Vol.118, №1. P.L5–L10.
6. Крылов О.В. Каталитическое окисление // Кинетика и катализ. 2002. Т.43, №2. С.310–316.
Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License (CC BY-NC-ND 4.0) that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.