Synthesis of bioethanol and products derived from it
Abstract
The paper represents an overview of methods for synthesis of ethanol, its properties, the information about its processing to produce valuable products for petrochemical and organic synthesis. The data on volumes of production and raw material base of bio ethanol production in different countries and its use as a bio fuel is shown. Catalytic conversion of ethanol allows to synthesize a number of valuable products such as fuels, olefins (mainly ethylene), aromatic hydrocarbons and gasoline range hydrocarbons. The directions and mechanism of the reactions of conversion of ethanol to ethylene, aromatic hydrocarbons and bivinyl, and the application of catalysts are examined. Much attention is paid to data on the development of a technology for catalytic conversion of bio ethanol to produce important products for the petrochemical industry. The problems of the development and production of alternative renewable raw materials - bio ethanol due to the depletion of oil reserves are discussed. Compared to an oil processing fuel, fuel produced from bio ethanol is cheaper and more environmentally friendly. The process is promising for Kazakhstan rich by plants, which can be used as raw materials for production of bio ethanol. The authors conduct the research on the production of olefins and aromatic hydrocarbons from bio ethanol using catalytic systems including cerium-containing catalysts and carriers based on zeolites (CaA, KA, NaA, NaX).
References
1 Tretyakov VT, Chang TK, Talychinsky RM, Ilolov AM, Frantsuzova NA (2013) Bulletin of the Moscow State University of Fine Chemical Technology [Vestnic Moskovskogo gosudarstvennogo universyteta tonkih himicheskih tehnologii] 40:509-514. (In Russian)
2 Iza Yusuf (2009) Conversion of the ethanol on zeolite catalysts [Konversiya etanola na tseolitnykh katalizatorakh]. Dissertation for Candidate of Technical Sciences Degree, Moscow, Russia. P.115-117. (In Russian)
3 Bukhanko N, Samikannu A, Larsson W, et al (2013) ACS Sustainable Chemistry and Engineering 1:8/883-893. http://dx.doi.org/10.1021/sc300171m
4 Caravaca A, De Lucas-Consuegra A, Calcerrada AB, Lobato JL, Dorado F (2013) Appl Catal B-Environ 134-135:302-309. http://dx.doi.org/10.1016/j.apcatb.2013.01.033
5 Topchiyeva AV, Tretyakov VT (2015) Bioethanol – The present situation and the future of petrochemicals. Alternativyne sources of raw materials. Collection of scientific papers. [Bioetanol - sostoyaniye i budushcheye v neftekhimii. Al’ternativyne istochniki syr’ya. Sbornik nauchnykh trudov.]. Belarusian science, Minsk, Byelorussia. P.14-17. (In Russian). ISNB 978-985-08-1728-0
6 Acheg ZA (2010) Technology of processing, storage and processing of cereal, bean cultures, groats products, horticultural products and wine growing [Nauchnoye obosnovaniye i razrabotka novoy tekhnologii polucheniye bioetanola]. Dissertation for Candidate of Technical Sciences Degree, Krasnodar, Russia. P.126-127. (In Russian)
7 Dosumov K, Ergaziyeva GE, Churina DСh (2012) Obtaining of hydrocarbons by catalytic conversion of ethanol [Polucheniye uglevodorodov kataliticheskoy konversiyey bioetanola]. Proceeding of The International Conference «Catalytic processes of oil refining, petrochemistry and ecology, Moscow, Russia. P.30-37. (In Russian)
8 Yakovlev VA, Khromova SA, Bukhtiyarov VI (2011) Russian Chemical Reviews 80:955-970. (In Russian)
9 Dorzhiyev SS, Pateeva IB.( 2011) Polzunovsky Bulletin [Polzunovskiy Vestnik] 2/2:251-253. (In Russian)
10 Bezruchic PP, Arbuzov YuD, Borisov GA (2002) The resources and efficiency of using renewable energy sources [Resursy i effektivnost’ ispol’zovaniya vozobnovlyayemykh istochnikov energii]. Science, Moscow, Russia. P.409-414. (In Russian)
11 Alternative energy [Alternanivnaya energetika] (2012). (In Russian). http://enegiya-prirpdy.com
12 Korotkova TG, Konstantinov EN Achegu ZA (2007) Proceedings of the Universities. Food Technology. [Izvestiya vuzov. Pishchevaya tekhnologiya] 5-6:105-106. (In Russian)
13 Arshinova A, Yakovlev V (2013) About biofuel prospects [O Perspektivah biotopliva]. (In Russian). http://www.computerra.ru/584522/
14 Sarsenbayev BA, Kirshibayev EA, Kamunur M, Bayseitova GA, Sarybayeva EA, Nokerbekova NK (2013) Biotechnology. Theory and Practic.[Biotehnologya. Teorya i practica] 3:61-64. (In Russian)
15 (2007) Chemicals from Ethanol, Process Economics Program Report 235. http://www.ihs.com/products/chemical-technology-pep-chemicals-from-ethanol-2007.html
16 Inui KT, Kurabayashi S (2002) Appl Catal A-Gen 237:53-61. http://dx.doi.org/10.1016/S0926-860X(02)00320-4
17 Das J, Halgeri AB (2003) Catal Surv Asia 7:3-9. http://dx.doi.org/10.1007/s10563-011-9112-1
18 Lebedev SV (1998) Life and transactions [Zhizn’ i trudy]. Leningrad-ONTI HIMTEORET, Leningrad, USSR. (In Russian). ISBN 879-3-450-77770-9
19 Bhattacharyya SK, Avasthi N (2003) J Appl Chem 2:45-51. http://dx.doi.org/10.1021/i260005a010
20 Hiroo N, Morii S, Echigoya E (2002) B Chem Soc Jpn. http://dx.doi.org/10.1002/02967419(02)90156-4
21 Dosumov Kh, Ergaziyeva GE, Churina DH, Telbayeva MM, Kalikhanov KK (2014) Chemical Bulletin of Kazakh National University 3:85-90. (In Russian). http://dx.doi.org/10.15328/chemb_2014_385-90
22 (2015) The International Congress “Biomass: Full and Energy” [Biomassa topliva y energetica]. (In Russian). http://www.biotoplovo.ru\html\news-bioethanol_1.html
23 Ghenciu AF (2002) Curr Opin Solid St M 6:389-399. http://dx.doi.org/10.1016/S1359-0286(02)00108-0
24 Kanaparthi R, Mei Hui L, Yi-Fan H, Borgna A (2009) Catal Commun 10:567-571. http://dx.doi.org/10.1016%2Fj.catcom.2008.10.034
25 Tretyakov VF, Lermontov AS, Makarfi Yu, Yakimova MS (2008) Chem Tech Fuels Oil+ 44: 409-414. http://dx.doi.org/10.1007/s10553-009-0077-y
26 Kapdan IK, Kargi F (2006) Enzyme Microb Tech 14:569-582. http://dx.doi.org/10.1016/j.enzmictec.2005.09.015
27 Siwale L, Kolesnikov A, Kristof L, et al (2013) Fuel 107:409-418. http://dx.doi.org/10.1016/j.esd.2009.10.001
28 Fan D, Dai DJ, Wu HS (2013) Materials 6:101-115. http://dx.doi.org/10.3390/ma6010101
29 Aguayo AT, Gayubo AG, Tarro AM, Atutxa A, Bilbao J (2002) J Chem Technol Biot 77:211-216. http://dx.doi.org/10.1002/jctb.540
30 Haveren VJ, Scott EL (2008) Biofuel Bioprod Bior 2:41-57. http://dx.doi.org/10.1002/bbb.43
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