Oxide catalysts for oxidation of xylene

  • Kusman Dossumov al-Farabi Kazakh National University
  • Dina Churina al-Farabi Kazakh National University
  • E. Tulibaev al-Farabi Kazakh National University
Keywords: catalyst, xylene, oxidation, activity, oxygen

Abstract

Polioxide granulated catalysts based on transition and rare earth metals for oxidative conversion of xylene by oxygen have been investigated. It was defined the effect of the composition and concentration of the active phase of oxide catalysts: Cu-Mn-Ln; Cu-Mn-Ce and Cu-Mn-Nd on the o-xylene oxidation. It was found that the Cu-Mn-Ce catalyst has the highest activity at the concentrations of metals: copper – 3.0%; manganese – 3.0%; cerium – 1.0%.

Author Biographies

Kusman Dossumov, al-Farabi Kazakh National University
Center of Physical Chemical Methods of Research and Analysis
Dina Churina, al-Farabi Kazakh National University
Center of Physical Chemical Methods of Research and Analysis
E. Tulibaev, al-Farabi Kazakh National University
Center of Physical Chemical Methods of Research and Analysis

References

1. Fairґen-Jimґenez D.; Carrasco-Marґın F.; and Moreno-Castilla C. Adsorption of Benzene; Toluene; and Xylenes on Monolithic Carbon Aerogels from Dry Air Flows. [Adsorbsiya benzola; toluola i ksilolov na monolitnih ugolnih aerogelyah iz suhih vozdushnih potokov]. American Chemical Society; Langmuir; 2007; 23. Р. 10095-10101.

2. Lorimier C.; Subrenat A.; Le Coq L. and Le Cloirec P. Adsorption of toluene onto activated carbonfibre cloths and felts: application to indoorair treatment. [Adsorbsiya toluola na aktivirovannoi uglevolokonnoi tkani i voiloke: primenenie dlya obrabotki vnutri doma]. Environmental Technology; 2005; 26. P. 1217-1230.

3. Lebiguea C.J.; Andriantsiferana C.; Krou N’G.; Ayral C.; Mohamed E.; Wilhelmay A-M; Delmas H.i; Le Coq L.; Gerente C.; Smith K. M.; Pullket S.; Fowler G.D.; Graham N.J.D. Application of sludge-based carbonaceous materials in a hybrid water treatment process based on adsorption and catalytic wet air oxidation. [Primenenie osadka na osnove uglerodsoderzhashih materialov v gibrinom processe ochistki vodi na osnove adsorbsii i kataliticheskogo okisleniya vlazhnim vozduhom]. Journal of Environmental Management; 2010; 9. P. 2432-2439.

4. Chianga H.L.; Huangb C.P.; Chiangc P.C.; Youd J.H. Effect of metal additives on the physico-chemical characteristics of activated carbon exemplified by benzene and acetic acid Adsorption [Vliyanie metallicheskih dobavok na fiziko-himicheskie harakteristiki aktivirovannogo ugleroda obrabotannogo adsorbciei benzola I uksusnoi kisloti]. Carbon; 1999; 37. P. 1919–1928.

5. Lillo-Roґdenas M.A.; Cazorla-Amoroґ D.; Linares-Solano A. Behaviour of activated carbons with different pore size distributions and surface oxygen groups for benzene and toluene adsorption at low concentrations. [Povedenie aktivirovannogo ugleroda s razlichnim raspredeleniem razmera por i poverhnostnimi kislorodnimi gruppami pri adsorbcii benzola i toluola pri nizkih konsentraciyah]. Carbon; 2005; 43. P.1758–1767.

6. Ming-Yen Wey; Wen-Yi Yang; and Hsing-Chung Huang; Jyh-Cherng Chen. Catalytic Oxidation of Organic Compounds in Incineration Flue Gas by a Commercial Palladium Catalyst [Kataliticheskoe okislenie organicheskih soedinenii pri szhiganii dimovih gazov na kommercheskom palladievom katalizatore]. Journal of the Air & Waste Management Association; 2002; 52. Р. 198-207.

7. Kerzhensev М.А.; Rogov V.А.; Kirichenko О.А. Study of adsorption characteristics of supported oxide catalyst for organic compounds existing in exhaust gases. [Issledovanie adsorbcionnih harakteristik nanesennih oksidnih katalizatorov po otnosheniyu k organicheskim soedineniyam prisutstvuyushim v gazovih vibrosah]. In digest: Disperse systems in environment protection technologyes. Мinsk; 1991. P. 48-59.

8. Vlasenko V.M.; Chernobrivets V.L.; Kurilets Ya.P. Study of sorption-catalytic purification of gases from epychlorhydrine over Cr oxide and Co-Cr catalysts. [Izuchenie sorbtsionno-katalyticheskoi ochistki gazov ot epihlorgidrina na oksidnohromovom i kobalthromovom katalizatorah]. Jurn. Prikl. Khimii – Journal of Applied Chemistry; 1999; 7. P.1142-1147.

9. Troshina V.A. Design and study of Mn-Al-Ca catalysts for the process of burning of organic impurities in exhaust gases: author's Ph.D. thesis. [Razrabotka i issledovanie marganetsalumokaltsievih katalizatorov dlya dozhiganiya organicheskih primesei v vibrosnih gazah: avtoreferat kand. disser]. 05.17.01. Моscow; 2003. 23 p.

10. Pat. USA 4234549; МПК В 01 D 53/42. [Pat. SShA 4234549; MPK В 01 D 53/42]. Pat. - 97108848/12; declared: 1997.05.21; published: 2000.04.20.

11. Patent of Russian Federation. The method of gases cleaning from toxic impurities. [Sposob ochistki gazov ot toksichnih primesei]. Zagoruiko A.N.; Noskov A.S.; the applicant and the patentee G.K.Boreskov Institute of Catalysis RAS.

Published
2013-09-14
How to Cite
Dossumov, K., Churina, D., & Tulibaev, E. (2013). Oxide catalysts for oxidation of xylene. Chemical Bulletin of Kazakh National University, 72(4), 31-37. https://doi.org/https://doi.org/10.15328/chemb_2013_431-37