Production of silver films on metal and dielectric surfaces

  • Perizat Abdurazova M.O. Auezov South Kazakhstan State University, Shymkent
  • Malik Satayev M.O. Auezov South Kazakhstan State University, Shymkent
  • Shayzada Koshkarbayeva M.O. Auezov South Kazakhstan State University, Shymkent
  • Aziza Kydyraliyeva M.O. Auezov South Kazakhstan State University, Shymkent
Keywords: silver films, copper films, metal surfaces, dielectric surfaces, fabric materials, bactericidal properties, porosity

Abstract

The given article contains the research results of processes of copper-phosphorus and silver-phosphorus films production on various surfaces and further transformation of these films in silver. Flat metal plates, flat and porous polymeric plates and also fabric materials have been used as samples. For improvement of wettability of surfaces by solutions, and also for intensification of adhesion the works connecting with preparation of the surfaces of the samples have been carried out. Films of copper and silver salts have been produced on these surfaces. For this purpose the samples have been dipped for some time in solutions of corresponding salts. It has been noticed, that a thickness of a film of the moistened sample depends on concentration of salt solutions. At change of concentration of the copper sulphate solution from 100 to 250 g/l, the film thickness has changed from 0,3 to 0,6 microns. For reduction of used salts in phosphides a phosphine-containing gas has been used. The given method can be applied for production of films on surfaces of products and internal pores of samples. In the process high adhesion of produced films can be reached.

References

1 Hoking М, Vasatasry V, Sidky P (2000) Metal and ceramic coverings: production, properties, application [Metallicheskiye i keramicheskiye pokrytiya: polucheniye, svoystva, primeneniye]. World, Moscow, Russia. P.518. (In Russian) ISBN:5­03­002570­7

2 Composition of a silver-containing catalyst, a way of the catalytic composition’s production and use of the catalytic composition for epoxidation of ethylene [Kompozitsiya katalizatora, soderzhashchego serebro, sposob polucheniya kataliticheskoy kompozitsii i ispol'zovaniye kataliticheskoy kompozitsii dlya epoksidirovaniya etilena]. Patent of the Russian Federation for an invention № 2333034 (2008.09.10). (In Russian)

3 Patent of the Russian Federation for an invention № 2257423 (27.07.2005). Open Company “Obninsk centre of a powder spraying”. (In Russian)

4 Krutjakov YuA, Kudrinskiy AA, Olenin AYu, Lisichkin GV (2008) Successes of chemistry 77(3):242-269. (In Russian) http://dx.doi.org/10.1070/RC2008v077n03ABEH003751

5 Hamburg YuD (2006) Galvanic coverings. Application handbook [Gal'vanicheskiye pokrytiya. Spravochnik po primeneniyu]. Technosphere, Moscow, Russia. P.216. (In Russian) ISBN:5-94836-079-2

6 Olenin AYu, Krutjakov YuA, Kudrinskiy AA, Lisichkin GV (2008) Colloid journal 70(1):78-84. (In Russian) http://dx.doi.org/10.1134/S1061933X08010110

7 Lomovsky OI, Boldyrev VV (1989) Applied Chemistry Journal 62(II):2444-2455. (In Russian)

8 Lomovsky OI, Zaikova IO (1986) Thermochomica Acta 92:645-648.

9 Perelshtein I, Applerot G, Perkas N, Guibert G, Mikhaylov S, Gedanken A (2008) Nanotechnology 19(24):5705. http://dx.doi.org/10.1088/0957-4484/19/24/245705

10  Shalkauskas MI, Vashkyalis AYu (2000) Chemical metallization of plastics [Khimicheskaya metallizatsiya plastmass]. Chemistry, St. Petersburg. P.144. (In Russian)

11   Liakumovich AG, Fridman BS, Zilberman AB, Guseva MS (1989) Plastics 2:40-43. (In Russian)

12  Technologies of repair, restoration, hardening and renewal of machines, mechanisms, equipment and metalwares (2002) Materials of the 4th All-Russian practical conference, St. Petersburg. P.136-140. (In Russian)

13  Sindeyev YuG (2000) Galvanic coverings. Phoenix, Moscow, Russia. P.251. (In Russian) ISBN: 5-222-01399-5

14  Vertelov GK, Krutyakov YuA, Efremenkova OV, Olenin AYu, Lisichkin GV (2008) Nanotechnology 19:355707. http://dx.doi.org/10.1088/0957-4484/19/35/355707

15   Lansdown AB, Silver I (2002) Journal of Wound Care 11:125-130. http://dx.doi.org/10.12968/jowc.2002.11.4.26389

16  Thomas S, McCubbin P (2003) Journal of Wound Care 12:101-107. http://dx.doi.org/10.12968/jowc.2003.12.3.26477

17  Margaret Ip, Sau Lai Lui, Vincent KM Poon, Ivan Lung, Andrew Burd (2006) Journal of Medical Microbiology 55:59-63. http://dx.doi.org/10.1099/jmm.0.46124-0

18  Darouiche, RO (1999) Clin Infect Dis 29:1371-1377. http://dx.doi.org/10.1086/313561

19  Furno F, Morley KS, Wong B et al. (2004) Journal of Antimicrobial Chemotherapy 54:1019-1024. http://dx.doi.org/10.1093/jac/dkh478

20  Volskiy NN, Seledtsov VI, Lyubimov GYu (1992) Immunomodulatory properties of colloid silver preparations. Colloid silver. Physical and chemical properties. Application in medicine [Immunomoduliruyushchiye svoystva preparatov kolloidnogo serebra. Kolloidnoye serebro. Fiziko-khimicheskiye svoystva. Primeneniye v meditsine]. Institute of Catalysis named after Boreskov G.K. of the Siberian branch of the Russian Academy of Sciences, Novosibirsk. P.31-52. (In Russian)

21  Artyomova A (2002) Silver heals and rejuvenates [Serebro istselyayet i omolazhivayet]. DILYA, Moscow - St. Petersburg. P.142. (In Russian)

22  Zyuzkevich SA (2007) Galvanic World 1:34. (In Russian)

23  Satayev MS, Koshkarbayeva Sh, Tukibayeva A, Tuleshova E (2013) Asian Journal of Chemistry 25(18):10301-10304.

24  Van Veser (1962) Phosphorus and its compounds [Fosfor i yego soyedineniya]. IL, Moscow, Russia. P.687. (In Russian)

Published
2015-03-31
How to Cite
Abdurazova, P., Satayev, M., Koshkarbayeva, S., & Kydyraliyeva, A. (2015). Production of silver films on metal and dielectric surfaces. Chemical Bulletin of Kazakh National University, (1), 64-71. https://doi.org/https://doi.org/10.15328/cb555
Section
Colloid and Nano Chemistry