Hydrogenation of acetyhlene alcohols on polymer-protected palladium catalysts

  • A. Zamanbekova Institute of Organic Catalysis and Electrochemistry named after D.V. Sokolsky, Almaty
  • B. Dyusenalin Institute of Organic Catalysis and Electrochemistry named after D.V. Sokolsky, Almaty
  • N. Tumabaev Institute of Organic Catalysis and Electrochemistry named after D.V. Sokolsky, Almaty
  • A. Zharmagambetova Institute of Organic Catalysis and Electrochemistry named after D.V. Sokolsky, Almaty
DOI: https://doi.org/10.15328/chemb_2011_497-100

Abstract

The conditions of preparation of polymer-protected palladium supported catalysts for hydrogenation of unsaturated alcohols have been studied. It was shown that the most convenient way to obtain low-percentage catalysts is low-temperature consequent adsorption of polymer and then metal on inorganic oxides. The temperature of catalyst preparation have an effect both on the size of formed metal nanoparticles and the catalytic properties. Palladium was reduced into aero-valence state when the preparation was ib the It is shown that in ethanol, in the presence of polybase (polyvinylpyridine), palladium is reduced into zero valence state by the ethanol. The optimum temperature for the catalyst preparation is in the range of 10-20ºC.

References

1 Жармагамбетова А.К., Курманбаева И.А., Комашко Л.В. Наноструктурные полимерметаллические катализаторы селективной гидрогенизации. Сборник докл. Междунар. конф. "Проблемы катализа XXI века" (памяти академика Д.В. Сокольского), 2001, с.82-91.

2 Дюсеналин Б.К. Нанесенные полимер-протектированные палладиевые нанокатализаторы гидрогенизации непредельных спиртов: – автореф. …канд. хим. наук. – Алматы, 2010.

Published
2011-12-01
How to Cite
Zamanbekova, A., Dyusenalin, B., Tumabaev, N., & Zharmagambetova, A. (2011). Hydrogenation of acetyhlene alcohols on polymer-protected palladium catalysts. Chemical Bulletin of Kazakh National University, 64(4), 97-100. https://doi.org/https://doi.org/10.15328/chemb_2011_497-100
Issue
Vol 64 No 4 (2011): Chemical Bulletin of Kazakh National University
Section
Other Papers
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