Use of radiation graft polymerization for modification of polypropylene
Abstract
The article investigates the process of applying the conductive layer on isotactic polypropylene modified by the radiation grafting monomer for improving the wettability of the surface. Presented IR spectra, the results of measuring the contact angle of the modified material indicate the improved surface hydrophilicity. The degree of grafting functional groups to the surface of isotactic polypropylene is determined. A scheme of gradual modification of polypropylene surface is presented. As the primary layer for the polymer metallization, copper-phosphorus film may be used. Copper-phosphorus films were obtained by reduction of copper compounds with phosphine gas. Experimental results show that the copper phosphide is electrically conductive coating and imparts an increased hardness.
References
1 Nazarov VG (2008) Surface modification of polymers: monograph [Poverhnostnaya modifikaciya polimerov: monografia]. MGUP, Moscow, Russia. (In Russian). ISBN 978-5-8122-0934-6.
2 Shalkauskas M, Vashkyalis A (1985) Chemical plating of plastics [Khimicheskaya metallizaciya plastmass]. Khimiya, Leningrad, USSR. (In Russian)
3 Povstugar VI, Kodolov VI, Mihailova SS (1988) The structure and the surfaceproperties of polymeric materials [Stroenie I svoistva poverhnosti polimernih materialov]. Khimiya, Moscow, USSR. (In Russian)
4 Petrova TP (2000) Soros Educational Journal [Sorosovskiy obozrevatelniy zhurnal] 11:78-83. (In Russian)
5 Ilin VA (1977) Metallization of dielectrics [Metallizatsiya dielektrikov]. Mashinostroenie, Leningrad, USSR. (In Russian)
6 Vershinina IA, Gornuhina OV, Golubchikov OA (2010) Plastic masses [Plasticheskie massi] 6:35-37. (In Russian)
7 Ishkov AV, Sagalakov AM (2006) Plastic masses [Plasticheskie massi] 12:10-13. (In Russian)
8 Markov VA (2015) Plastic masses [Plasticheskie massi] 1/2:13-17. (In Russian)
9 Inzelt G (2008) Conducting polymers. A new era in electrochemistry. Springer, Berlin, Germany. ISBN 978-3-642-27621-7
10 Koshkarbaeva ShT, Nauryzova SZ, Sataev MS, Tleuova AB (2012) Oriental Journal of Chemistry 28:1281-1284.
11 Sataev MS, Koshkarbaeva ShT, Perni S, Nauryzova SZ, Prokopovich P (2015) Colloid Surface A 480:384-389. http://dx.doi.org/10.1016/j.colsurfa.2014.09.014
12 Nauryzova SZ, Sataev MS, Koshkarbaeva Sh T (2015) Chemical and electrochemical method of obtaining composite coatings [Khimiko-galvanicheskiy metod polucheniya kombinirovannih pokritii]. Materials of the XIX Mendeleev Congress on General and Applied chemistry, Volgograd, Russia. Part 2.
13 Sataev MS, Koshkarbaeva ShT, Nauryzova SZ, Kozhakulov NK, Amanbayeva KB, Aueshov AP (2011) Method of obtaining composite coatings [Metod polucheniya kompozicionnih pokritii]. Innovational Patent of the Republic of Kazakhstan No.25319 [Innovacioniy patent Respubliki Kazakhstan №25319]. (In Russian)
14 Guven O, Alacakir A, Tan E (1997) Radiat Phys Chem 50:165-170. http://dx.doi.org/10.1016/S0969-806X(97)00002-9
15 Povstugar VI, Kodolov VI, Mihailova SS (1988) The structure and the surface properties of polymeric materials [Stroenie I svoistva poverhnosti polimernih materialov]. Khimiya, Moscow, USSR. (In Russian). ISBN 5-7245-0115-5
16 Krul LP, Polikarpov AP (1990) Russ Chem Rev 59:807-826. (In Russian). http://dx.doi.org/10.1070/RC1990v059n05ABEH003537
17 Nauryzova SZ, Iztleuova M, Yeligbayeva GZh (2015) Industry of Kazakhstan [Promishlennost Kazakhstana] 1:85-88.
18 Krompton T (1988) Analysis of plastics [Analiz plastikov]. Trans. Maslova SA, ed. Zaikova GA. Mir, Mosсow, USSR. P.679. (In Russian)
19 Tarasevich BN (2012) Basics of IR spectroscopy with Fourier transform. Sample preparation Infrared spectroscopy [Osnovi IK-spektroskopii c pereobrazovaniem Fure. Podgotovka prob v IK-spektroskopii]. M.V. Lomonosov MGU, Moscow, Russia. P.222. (In Russian)
20 Kukushkin UN (1997) Chemical molecules coordinated with metal ions [Khimiya
molekul, koordinirovannih ionami metallov]. Khimya, Saint Petersburg, Russia. (In Russian)
21 Lashko NF, Lashko SV (1977) Metal soldering [Paika metallov]. Mashinostroenie, Moscow, USSR. P87. (In Russian).
22 Tsetlin BL, Golubev VN, Vlasov AV, Khokhlov AR, Vannikov AV, Tameev AR (2004) Macromol Rapid Comm 25:628-361. http://dx.doi.org/10.1002/marc.200300201
23 Sataev MS, Daurenbekova LM (1994) The manufacturing method of the nickel oxide electrode [Sposob izgotovleniya oksidno-nikelevogo elektroda]. Patent of the Republic of Kazakhstan No.12758 [Patent Respubliki Kazakhstan №12758]. (In Russian)
24 (2003) Metals and alloys. Directory [Metalli i splavi. Spravochnik]. ANO NPO “Professional”, Saint Petersburg, Russia. (In Russian)
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License (CC BY-NC-ND 4.0) that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
