Production of olefins from bioethanol. Catalysts, mechanism

  • Kusman Dossumov BSE Scientific Research Institute of New Chemical Technologies and Materials of the RSE al-Farabi Kazakh National University, Almaty
  • Dina Churina BSE Scientific Research Institute of New Chemical Technologies and Materials of the RSE al-Farabi Kazakh National University, Almaty
  • G. Еrgazieva BSE Scientific Research Institute of New Chemical Technologies and Materials of the RSE al-Farabi Kazakh National University, Almaty
  • Galina Аbramova BSE Scientific Research Institute of New Chemical Technologies and Materials of the RSE al-Farabi Kazakh National University, Almaty
  • М. Теlbayeva BSE Scientific Research Institute of New Chemical Technologies and Materials of the RSE al-Farabi Kazakh National University, Almaty
Keywords: natural gas, bioethanol, technology, fuel, alkenes

Abstract

This review describes methods of catalytic obtaining from bioethanol of valuable industrial products – olefins, particularly ethylene. Аmong olefins, ethylene is the most popular key raw material of petrochemical synthesis. The scope of appllication of ethylene is almost unlimited in petrochemical products: polyethylene, ethylbenzene, styrene, ethylene dichloride, vinyl chloride etc. It also examines catalysts for the production of olefins and their properties. The most promising and commercially advantageous process of ethylene production by catalytic dehydration of ethanol on catalysts based on modified alumina. And this review discusses the mechanisms of catalytic conversion of ethanol to ethylene.

References

1. Zervos A., Lius Сh., Schrafer O. Tomorrow's world // Renewable energy world. – 2004. – Vol.7. – № 4. – P. 21-26.

2. Tretiyakov V.F., Lermontov A.S., Makarfi Yu. I., Yakimova M.S, Frantsuzova N.A., Shoe-smith L.М., Erofeev V.I. Synthesis of motor fuels from a bioethanol // Chemistry and technology of fuels and oils. – 2008. – № 6. – P. 30-34.

3. Petrov А.А., Baliyan H.V., Тroshenko А.Т. Organic chemistry. – M.: Higher school, 1981. – P. 69-72.

4. Lee K - Y., Chae H - J., Jeong S - Y., Seo G. Effect of crystallite size of SAPO - 34 catalysts on their induction period and deactivation in methanol - to - olefin reactions // Applied Catalysis (A: General). – 2009. – Vol. 369. – № 1-2. – P. 60-66.

5. Montoya A., del Angela P., Viveros T. The effect of temperature on the structural and textural evolution of sol - gel A1203 - Ti02 mixed oxides // J. Mater. Chem. – 2001. – Vol. 11. – P. 944-950.

6. Inamura S., Miyamoto H., Imaida Y., Takagawa M., Hirota K., Yamaguchi O. Formation and hot isostatic pressing of Zr02 solid solution in the system Zr02 - A1203 // J. of Mater. Science. – 1994. – Vol. 281. – P. 4913-4917.

7. Zotov R.A., Моlchanov V.V., Goidin V.V., Moroz E.М., Volodin A.M. Development of methods of preparation of the modified aluminiumoxide catalysts and study of their properties // Kinetics and catalysis. – 2010. – Vol. 51. – № 1. – P. 149-152.

8. Wu L - P., Li X - J., Yuan Zh - H., ChenY. The fabrication of Ti02 - supported zeolite with core/shell heterostructure for ethanol dehydration to ethylene // Catalysis Communications. – 2009. – Vol. 11. – № 1. – P. 67-70.

9. Chen G., Li Sh., Jiao F., Yuan Q. Catalytic dehydration of bioethanol to ethylene over Ti02/g - A1203 catalysts in microchannel reactors // Catalysis Today. – 2007. – Vol. 125. – P. 111-119.

10. Bi J., Guo X., Liu M., Wang X. High effective dehydration of bio - ethanol into ethylene over nanoscale HZSM - 5 zeolite catalysts // Catalysis Today. – 2010. – Vol. 149. – № 1-2. – P. 143-147.

11. Varisli D., Dogu Т., Dogu G. Ethylene and diethyl - ether production by dehydration reaction of ethanol over different heteropolyacid catalysts // Chemical Engineering Science. – 2007. – Vol. 62. – P. 5349-5352.

12. Solinas V., Rombi E., Ferino I., Cutrufello M.G., Colón G., Navio J.A. Preparation, characterisation and activity of Ce02 - Zr02 catalysts for alcohol dehydration // Journal of Molecular Catalysis (A : Chemical). – 2003. – Vol. 204-205. – P. 629-635.

13. Zhang X., Wang R., Yang X., Zhang F. Comparison of four catalysts in the catalytic dehydration of ethanol to ethylene // Microporous and Mesoporous Materials. – 2008. – Vol. 116. – P. 210-215.

14. Tretiyakov V.F., Burdeinaiya Т.N., Lermontov A.S., Makarfi Yu. I., Yakimova M.S. A Bioethanol is proceeded in the alternative source of motor fuels and organic compounds // Theses of the All-Russian conference with international participation "Catalytic technologies of defence of environment for industry and transport". – Saint Petersburg, 2007. – P. 139 - 140.

15. Balandin А.А. Modern state of multyplete theory of heterogeneous catalysis. – М.: Science, 1968. – 202 p. 16. Krylov О.V. Catalysis by non-metals. Conformities to law of selection of catalysts. – L.: Chemistry, 1967. – P. 88.

17. Germen J. Catalytic transformations of hydrocarbons. – M.: World, 1972. – 308 p.

18. Makarfi Yu. I., Tretiyakov V.F., Frantsuzova N.A., Shoe-smith L.М., Erofeev V.I., Trushin A.A. Conversion of ethanol and water-ethanol mixtures on the industrial catalyst of HZSM – 5 // Announcer МIТChТ. – 2009. – Vol. 4. – № 5. – P. 52-55.

19. Makarfi Yusuf Isa, Yakimova M.S, Lermontov A.S., Erofeev V.I., Koval L.M., Tretiyakov V.F. Оn version of Bioethanol over zeolites // Chemical Engineering Journal. – 2009. – Vol. 154. – № 1-3. – P. 396 - 400.

 

Cited by: 1

1. Shuai L, Luterbacher J (2015) Organic solvent effects in biomass conversion reactions. ChemSusChem 9:133-155. CrossRef

Published
2012-12-04
How to Cite
Dossumov, K., Churina, D., ЕrgazievaG., АbramovaG., & ТеlbayevaМ. (2012). Production of olefins from bioethanol. Catalysts, mechanism. Chemical Bulletin of Kazakh National University, (4), 42-49. https://doi.org/https://doi.org/10.15328/chemb_2012_442-49
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Other Papers