Comparative analysis of coal tar hydrogenation

  • M. Baikenov E.A. Buketov Karaganda State University, Karaganda
  • Zh. Akhmetkarimova E.A. Buketov Karaganda State University, Karaganda
  • A. Tussiphan E.A. Buketov Karaganda State University, Karaganda
  • Feng Ma Xinjiang University, Urumqi
Keywords: primary coal tar, hydrogenation, of iron-based nanocatalyst, activity, selectivity

Abstract

One of the most promising and important trends is the hydrogenation of PCT and its broad factions. However, the direct processing of PCT and its fractions is difficult due to the high content of phenols and aromatic hydrocarbons. In order to determine the kinetic parameters of PCT fractions hydrogenation using nanocatalyst synthesis of iron-based nanocatalyst was carried out.  Hydrogenation process in the presence of nano-catalysts was utilized. The size of solid residue surfaces and the liquid products yield were determined. The synthesized nanocatalyst showed high activity and selectivity at the hydrogenation process.

References

1. Kautman M., Jamison W.C. Coal liquefaction in fluorocarbon medium. Fuel. 2006 . 1. P. 148-150

2. Gudun KA, Baikenov MI, Tusiphan A., Ma Feng Yun . Catalytic hydrogenation in the presence of model objects nanocatalysts β-FeOOH. Actualne problemy nowoczesnych nauk. 2012: Materiały VIII międzynarodowej naukowi-praktycznej konferencji. 44. Fizyka, Chemia a chemiczne technologie. Przemyśl: Nauka i studia, 2012. P. 87-91.

3. Chistyakov A.N. Chemistry and technology of coal tar. [Himija i tehnologija pererabotki kamennougol'nyh smol].Chelyabinsk: Metallurgy. Chelyabinsk branch, 1990. 160 P.

4. Gogoleva T.J., Shustikov V.I. Chemistry and processing of coal tar. [Himija i pererabotka kamennougol'noj smoly]. Moscow: Metallurgy, 1992, 256 p.

5. RK patent no 6900, Karasev N.I., Kuchin V.N., Okrut I.I. 1995, Hydrodynamic heater.

6. http://www.akorda.kz

7. Baikenov M.I., Amerkhanova Sh.K., Уali A.S. Method of extraction of phenols from coal tar by extraction and cavitation treatment . Conclusion extradition innovative patent for invention number 022739. 08.09.2011. MJ RK .

8. Golovin, GS, AS Maloletnev Complex processing of coal and increase their effectiveness [Kompleksnaja pererabotka uglej i povyshenie jeffektivnosti ih ispol'zovanija] Edited by V.M. Shchadov. Moscow, 2007, 292 p.

9. Gudun K.A., Baikenov M.I., Ma Feng-yun. Hydrogenation of a model mixture of anthracene with benzothiophene. Solid Fuel Chemistry. 2010. 44, 6. P. 419-422.

10. Hazhdiev S.N., Liadov A.S., Krylov M.V., Krylov A. Fischer-Tropsch synthesis in a three-phase system in the presence of nanoscale catalysts [Sintez Fishera-Tropsha v trehfaznoj sisteme v prisutstvii nanorazmernyh katalizatorov]. Neftehimija – Petroleum chemistry, 2011. 51, 2. P.84 -95.

11. Jongnum Park Hwangjinanet. al Ultra-large-scale syntheses of monodisperse nanocrystals. Nature Publishing Group, 2004. 12. P.891 -895.

12. Dilnur Talifu, Fengyun Ma, Yuan Xue. The heat recovery equipment design of primary furnace / exhaust gas: coil heat exchanger. The Herald KSU. 2011. 4 (62). P.64- 68.

13. Lyubimenko V.A., Petrukhina N.N., Tumanyan B.P., Kolesnikov I.M. Thermodynamic parameters of conversion reactions of some components of heavy oils with steam stimulation [Termodinamicheskie parametry reakcij prevrashhenija nekotoryh komponentov tjazhelyh neftej pri paroteplovom vozdejstvii]. Himija i tehnologija topliv i masel – Chemistry and technology of fuels and oils. 2012. 4. P.27-33.

14. Katritzky A.R., Nichols D.A., Siskm M. et al Reactions in high-temperature aqueous media. Chem Rev. 2001 . 101, 4 . P.837- 892.

Published
2014-04-28
How to Cite
Baikenov, M., Akhmetkarimova, Z., Tussiphan, A., & Ma, F. (2014). Comparative analysis of coal tar hydrogenation. Chemical Bulletin of Kazakh National University, 73(1), 14-20. https://doi.org/https://doi.org/10.15328/chemb_2014_114-20