Obtaining of luminescent material based on NaBaY(BO3)2 doped with terbium and europium ions

  • Zhandos K. Orazov Center of Physical Chemical Methods of Research and Analysis, Al-Farabi Kazakh National University, Almaty, Kazakhstan https://orcid.org/0000-0002-6562-6093
  • Asset K. Bolatov Center of Physical Chemical Methods of Research and Analysis, Al-Farabi Kazakh National University, Almaty, Kazakhstan https://orcid.org/0000-0002-9677-2114
  • Nadezhda G. Kononova Sobolev Institute of Geology and Mineralogy Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia
  • Vyacheslav S. Shevchenko Sobolev Institute of Geology and Mineralogy Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia
  • Konstantin A. Kokh Sobolev Institute of Geology and Mineralogy Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia; Novosibirsk State University, Novosibirsk, Russia
  • Bolat M. Uralbekov Center of Physical Chemical Methods of Research and Analysis, Al-Farabi Kazakh National University, Almaty, Kazakhstan https://orcid.org/0000-0002-3245-4096
  • Artem B. Kuznetsov obolev Institute of Geology and Mineralogy Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia
  • Aleksandr E. Kokh Sobolev Institute of Geology and Mineralogy Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia
Keywords: NaBaY(BO3)2:0.07Tb3 :0.1Eu3, crystal structure, doping, luminescent material

Abstract

A new luminescent material based on complex borate NaBaY(BO3)2 doped with Tb3+ and Eu3+ ions was obtained by high-temperature solid-state synthesis. Using X-ray diffraction analysis it was shown that NaBaY(BO3)2:0.07Tb3+:0.1Eu3+ crystallizes in trigonal system with the space group R-3m and isotypic with the mineral buetschliit K2Ca(CO3)2. The crystal structure of the phosphor is layered, formed from [BO3] triangles, [YO6] octahedra, [BaO9] and [NaO9] polyhedra. The calculated unit cell parameters for NaBaY(BO3)2:0.07Tb3+:0.1Eu3+ are: a=5.3510(6) Å, c=17.9338(3) Å, V=444.71(2) Å3. The luminescent properties of NaBaY(BO3)2:0.07Tb3+:0.1Eu3+ were studied.

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Published
2020-05-19
How to Cite
Orazov, Z., Bolatov, A., Kononova, N., Shevchenko, V., Kokh, K., Uralbekov, B., Kuznetsov, A., & Kokh, A. (2020). Obtaining of luminescent material based on NaBaY(BO3)2 doped with terbium and europium ions. Chemical Bulletin of Kazakh National University, (2), 10-15. https://doi.org/https://doi.org/10.15328/cb1122
Section
Inorganic Chemistry