Study of the kinetics of palladium catalysts with 2-metoxy-naphtyl-diferrocenyl-, 2-tert-butyl-oxiphenyl-diferrocenyl-phosphine and 1,1’-diphenyl-phosphin-ferrocene ligands

  • Alibek Khabiyev Kazakh National Technical University named after K.I. Satpayev, Almaty
  • Bagadat Selenova Kazakh National Technical University named after K.I. Satpayev, Almaty
  • Heinrich Lang Chemnitz University of Technology, Chemnitz
  • Christian Gaebler Chemnitz University of Technology, Chemnitz
DOI: https://doi.org/10.15328/chemb_2014_213-18
Keywords: palladium catalysts, C, C-cross-coupling reactions, Suzuki-Miyara reaction, homogeneous catalysis

Abstract

The article presents results of the study on kinetic of palladium catalyst with 2-metoxy-naphtyl-diferrocenyl-, 2-tret-butyl-oxiphenyl-diferrocenyl-phosphin and 1,1’-diphenyl-phosphin-ferrocen ligands in Suzuki-Miyara test-reactions. The advantage of Suzuki reactions in difference from other cross-coupling reactions is the use of insensitive to water and oxygen thermostable organoboron compounds. As boronic acid was used phenylboronic acid and as weak base – potassium phosphate. All used catalysts showed good activity with arylbromides and weak activity with arylchlorides.

Author Biography

Alibek Khabiyev, Kazakh National Technical University named after K.I. Satpayev, Almaty
Ph.D. student

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Published
2014-08-14
How to Cite
Khabiyev, A., Selenova, B., Lang, H., & Gaebler, C. (2014). Study of the kinetics of palladium catalysts with 2-metoxy-naphtyl-diferrocenyl-, 2-tert-butyl-oxiphenyl-diferrocenyl-phosphine and 1,1’-diphenyl-phosphin-ferrocene ligands. Chemical Bulletin of Kazakh National University, 74(2), 13-18. https://doi.org/https://doi.org/10.15328/chemb_2014_213-18
Issue
Vol 74 No 2 (2014): Chemical Bulletin of Kazakh National University
Section
Catalysis and Petrochemistry
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