Use of radiation graft polymerization for modification of polypropylene

  • Saule Zinagievna Nauryzova K.I. Satpayev Kazakh National Research Technical University, Almaty
  • Еrengaip Shaihutdinov K.I. Satpayev Kazakh National Research Technical University, Almaty
  • Gulghahan Yeligbayeva M. Auezov South-Kazakhstan State University, Shymkent
  • Malik Sybambaevich Satayev M. Auezov South-Kazakhstan State University, Shymkent
  • Shaizada Koshkarbayeva M. Auezov South-Kazakhstan State University, Shymkent

Abstract

The article investigates the process of applying the conductive layer on isotactic polypropylene modified by the radiation grafting monomer for improving the wettability of the surface. Presented IR spectra, the results of measuring the contact angle of the modified material indicate the improved surface hydrophilicity. The degree of grafting functional groups to the surface of isotactic polypropylene is determined. A scheme of gradual modification of polypropylene surface is presented. As the primary layer for the polymer metallization, copper-phosphorus film may be used. Copper-phosphorus films were obtained by reduction of copper compounds with phosphine gas. Experimental results show that the copper phosphide is electrically conductive coating and imparts an increased hardness.

 

References

1  Nazarov VG (2008) Surface modification of polymers: monograph [Poverhnostnaya modifikaciya polimerov: monografia]. MGUP, Moscow, Russia. (In Russian). ISBN 978-5-8122-0934-6.

2  Shalkauskas M, Vashkyalis A (1985) Chemical plating of plastics [Khimicheskaya metallizaciya plastmass]. Khimiya, Leningrad, USSR. (In Russian)

3  Povstugar VI, Kodolov VI, Mihailova SS (1988) The structure and the surfaceproperties of polymeric materials [Stroenie I svoistva poverhnosti polimernih materialov]. Khimiya, Moscow, USSR. (In Russian)

4  Petrova TP (2000) Soros Educational Journal [Sorosovskiy obozrevatelniy zhurnal] 11:78-83. (In Russian)

5  Ilin VA (1977) Metallization of dielectrics [Metallizatsiya dielektrikov]. Mashinostroenie, Leningrad, USSR. (In Russian)

6  Vershinina IA, Gornuhina OV, Golubchikov OA (2010) Plastic masses [Plasticheskie massi] 6:35-37. (In Russian)

7  Ishkov AV, Sagalakov AM (2006) Plastic masses [Plasticheskie massi] 12:10-13. (In Russian)

8  Markov VA (2015) Plastic masses [Plasticheskie massi] 1/2:13-17. (In Russian)

9  Inzelt G (2008) Conducting polymers. A new era in electrochemistry. Springer, Berlin, Germany. ISBN 978-3-642-27621-7

10  Koshkarbaeva ShT, Nauryzova SZ, Sataev MS, Tleuova AB (2012) Oriental Journal of Chemistry 28:1281-1284.                                                                                                  

11  Sataev MS, Koshkarbaeva ShT, Perni S, Nauryzova SZ, Prokopovich P (2015) Colloid Surface A 480:384-389. http://dx.doi.org/10.1016/j.colsurfa.2014.09.014

12  Nauryzova SZ, Sataev MS, Koshkarbaeva Sh T (2015) Chemical and electrochemical method of obtaining composite coatings [Khimiko-galvanicheskiy metod polucheniya kombinirovannih pokritii]. Materials of the XIX Mendeleev Congress on General and Applied chemistry, Volgograd, Russia. Part 2.  

13  Sataev MS, Koshkarbaeva ShT, Nauryzova SZ, Kozhakulov NK, Amanbayeva KB, Aueshov AP (2011) Method of obtaining composite coatings [Metod polucheniya kompozicionnih pokritii]. Innovational Patent of the Republic of Kazakhstan No.25319 [Innovacioniy patent Respubliki Kazakhstan №25319]. (In Russian)    

14   Guven O, Alacakir A, Tan E (1997) Radiat Phys Chem 50:165-170. http://dx.doi.org/10.1016/S0969-806X(97)00002-9

15  Povstugar VI, Kodolov VI, Mihailova SS (1988) The structure and the surface properties of polymeric materials [Stroenie I svoistva poverhnosti polimernih materialov]. Khimiya, Moscow, USSR. (In Russian). ISBN 5-7245-0115-5

16  Krul LP, Polikarpov AP (1990) Russ Chem Rev 59:807-826. (In Russian). http://dx.doi.org/10.1070/RC1990v059n05ABEH003537

17  Nauryzova SZ, Iztleuova M, Yeligbayeva GZh (2015) Industry of Kazakhstan [Promishlennost Kazakhstana] 1:85-88.

18  Krompton T (1988) Analysis of plastics [Analiz plastikov]. Trans. Maslova SA, ed. Zaikova GA. Mir, Mosсow, USSR. P.679. (In Russian)

19  Tarasevich BN (2012) Basics of IR spectroscopy with Fourier transform. Sample preparation Infrared spectroscopy [Osnovi IK-spektroskopii c pereobrazovaniem Fure. Podgotovka prob v IK-spektroskopii]. M.V. Lomonosov MGU, Moscow, Russia. P.222. (In Russian)

20  Kukushkin UN (1997) Chemical molecules coordinated with metal ions [Khimiya

molekul, koordinirovannih ionami metallov]. Khimya, Saint Petersburg, Russia. (In Russian)

21  Lashko NF, Lashko SV (1977) Metal soldering [Paika metallov]. Mashinostroenie, Moscow, USSR. P87. (In Russian).

22  Tsetlin BL, Golubev VN, Vlasov AV, Khokhlov AR, Vannikov AV, Tameev AR (2004) Macromol Rapid Comm 25:628-361. http://dx.doi.org/10.1002/marc.200300201

23  Sataev MS, Daurenbekova LM (1994) The manufacturing method of the nickel oxide electrode [Sposob izgotovleniya oksidno-nikelevogo elektroda]. Patent of the Republic of Kazakhstan No.12758 [Patent Respubliki Kazakhstan №12758]. (In Russian)

24  (2003) Metals and alloys. Directory [Metalli i splavi. Spravochnik]. ANO NPO “Professional”, Saint Petersburg, Russia. (In Russian)

Published
2016-10-13
How to Cite
NAURYZOVA, Saule Zinagievna et al. Use of radiation graft polymerization for modification of polypropylene. Chemical Bulletin of Kazakh National University, [S.l.], n. 2, p. 46-54, oct. 2016. ISSN 2312-7554. Available at: <http://bulletin.chemistry.kz/index.php/kaznu/article/view/691>. Date accessed: 24 june 2017. doi: https://doi.org/10.15328/cb691.
Section
Catalysis and Petrochemistry

Keywords

modification; radiation grafting; hydrophility; wettability; copper phosphide