Liquid-phase oxygenation of toluene on a metal-complex catalyst of copper (II) immobilized in a polymer

  • Gulnarhan Kurmangazhy I. Zhansugurov Zhetysu State University, Taldykurgan
  • Zhaneta Tashmukhambetova al-Farabi Kazakh National University http://orcid.org/0000-0002-2967-9366
  • Ilias Esengabylov I. Zhansugurov Zhetysu State University, Taldykurgan
  • Raikhan Rakhmetullaeva al-Farabi Kazakh National University
DOI: https://doi.org/10.15328/cb606
Keywords: catalyst, metal complexes, toluene, hydrogel, immobilization, the process of oxidation

Abstract

The use of immobilized catalysts based on complexes of transition metals in the oxidation process has great importance nowadays. Polymeric metal complex catalysts for petrochemical processes taking place in the liquid phase are environmentally effective and safe. This paper presents the data on oxidation process of toluene in the liquid phase under mild conditions using a catalyst. A metal complex of copper (II) immobilized in hydrogel based on thermally stable copolymer of dimethylaminoethylmethacrylate and hydroxyethylacrylate (30:70) is used as the most optimal catalyst. Experiment on toluene oxidation was reproduced several times. The relative deviation of the experiment was 3-4%. According to the infrared и ultraviolet spectrum, toluene peroxide is the main product of toluene oxygenation. The conversion of toluene within 90 min was 95%.

References

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Published
2015-10-18
How to Cite
Kurmangazhy, G., Tashmukhambetova, Z., Esengabylov, I., & Rakhmetullaeva, R. (2015). Liquid-phase oxygenation of toluene on a metal-complex catalyst of copper (II) immobilized in a polymer. Chemical Bulletin of Kazakh National University, 78(2), 78-82. https://doi.org/https://doi.org/10.15328/cb606
Issue
Vol 78 No 2 (2015): Chemical Bulletin of Kazakh National University
Section
Catalysis and Petrochemistry
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